![]() ![]() Among the compounds derived from HNT, perchlorate 7 exhibits remarkable properties, with a high density of 1.95 g cm −3 and an outstanding detonation velocity (9505 m s −1) and pressure (419 GPa), thus surpassing RDX in performance. Densities and enthalpies of formation of compounds 3-4, 6–8 and 12–15 were measured and the respective P CJ and D CJ were calculated using these experimental data. Its specific amphoteric properties were demonstrated through the synthesis of both cationic and anionic salts. HNT was found to represent a valuable platform towards powerful and thermally stable energetic compounds. Here is described the first synthesis of 5-hydrazino-3-nitro-1,2,4-triazole ( HNT), as a free base, from 5-bromo-3-nitro-1,2,4-triazole ( BNT) in three steps.
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